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9093213

Cc1oc(=O)oc1COC(=O)C1=C(SC2CCNC2=O)[C@H](C)[C@@H]2[C@@H]([C@@H](C)O)C(=O)N12

Ausbeute 45.7%DOI: 10.6084/m9.figshare.5104873.v1

CC(OC(=O)OC1CCCCC1)OC(=O)C1=C(SC2CNC(=O)C2)[C@H](C)[C@@H]2[C@@H]([C@@H](C)O)C(=O)N12

DOI: 10.6084/m9.figshare.5104873.v1

Cc1oc(=O)oc1COC(=O)C1=C(SC2CNC(=O)C2)[C@H](C)[C@@H]2[C@@H]([C@@H](C)O)C(=O)N12

Ausbeute 79.5%DOI: 10.6084/m9.figshare.5104873.v1

CSCC1=C(C(=O)[O-])N2C(=O)C(NC(=O)C(=NO)c3csc(N)n3)[C@H]2SC1.[Na+]

sodium 3-methylthiomethyl-7-[2-(2-amino-4-thiazolyl)-2-hydroxyimino-acetamido]-ceph-3-eme-4-carboxylate

DOI: 10.6084/m9.figshare.5104873.v1

$CO/N=C(\C(=O)N[C@@H]1C(=O)N2C(C(=O)OCOC(=O)C(C)(C)C)=C(C3CCC(=O)O3)CS[C@H]12)c1csc(N)n1$

Ausbeute 59.1%DOI: 10.6084/m9.figshare.5104873.v1

C=CC(=O)[Si](OCC)(OCC)OCC

Reaction #12076

acryltriethoxysilane

DOI: 10.6084/m9.figshare.5104873.v1

CCOC(=O)C(C(=O)NC1C(=O)N2C(C(=O)OCOC(=O)C(NC(=O)OC(C)(C)C)C(C)C)=C(COC(C)=O)CSC12)n1cccc1

Reaction #54600

3-[(acetyloxy)methyl]-7-[[2-carboethoxy-2-(1-pyrryl)acetyl]-amino]-8-oxo-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylic acid N-tert-butoxycarbonyl-2-amino-3-methylbutyryloxymethyl ester

DOI: 10.6084/m9.figshare.5104873.v1

Cc1ccc(S(=O)(=O)NC(=O)c2ccccc2C(=O)OCC2=C(C(=O)[O-])N3C(=O)[C@@H](NC(=O)Cc4cccs4)[C@H]3SC2)cc1.[Na+]

Reaction #56294

7β-(2-thienylacetamido)-3-[2-(N-tosylcarbamoyl) benzoyloxy]methyl-3-cephem-4-carboxylic acid sodium salt

Ausbeute 58.5%DOI: 10.6084/m9.figshare.5104873.v1

CCOC(=O)NS(=O)(=O)c1ccccc1C(=O)OCC1=C(C(=O)O)N2C(=O)[C@@H](NC(=O)OC(C)(C)C)[C@H]2SC1

Reaction #56296

7β-(t-butoxycarbonyl)amino-3-[2-(N-carboethoxysulfamoyl)benzoyloxy]methyl-3-cephem-4-carboxylic acid

Ausbeute 47.0%DOI: 10.6084/m9.figshare.5104873.v1

Cc1ccc(S(=O)(=O)NC(=O)c2ccccc2C(=O)OCC2=C(C(=O)O)N3C(=O)[C@@H](NC(=O)OC(C)(C)C)[C@H]3SC2)cc1

Reaction #56300

7β-(t-butoxycarbonyl)amino-3-[2-(N-tosylcarbamoyl)benzoyloxy]methyl-3-cephem-4-carboxylic acid

Ausbeute 42.2%DOI: 10.6084/m9.figshare.5104873.v1

Cc1nnc(SCC2=C(C(=O)[O-])N3C(=O)[C@@H](NC(=O)Cn4cnnn4)[C@H]3SC2)s1.[Na+]

Reaction #56303

sodium 7β-(1H-tetrazol-1-yl)acetamido-3-(2-methyl-1,3,4-thiadiazol-5-yl)thiomethyl-3-cephem-4-carboxylate

DOI: 10.6084/m9.figshare.5104873.v1

CON=C(C(=O)NC1C(=O)N2C(C(=O)[O-])=CC(C)S[C@H]12)c1csc(N)n1.[Na+]

Reaction #56576

sodium 2-methyl-7-[2-methoxyimino-2-(2-aminothiazol-4-yl)acetamido]-3-cephem-4-carboxylate

DOI: 10.6084/m9.figshare.5104873.v1

CON=C(C(=O)NC1C(=O)N2C(C(=O)OCOC(=O)C(C)(C)C)=CC(C)S[C@H]12)c1csc(N)n1

Reaction #56577

pivaloyloxymethyl 2-methyl-7-[2-methoxyimino-2-(2-aminothiazol-4-yl)acetamido]-3-cephem-4-carboxylate

DOI: 10.6084/m9.figshare.5104873.v1

$CCOC(=O)OC(C)OC(=O)C1=C(CSc2nc(C)ns2)CS[C@@H]2C(NC(=O)/C(=N\OC)c3cscn3)C(=O)N12$

Reaction #62542

DOI: 10.6084/m9.figshare.5104873.v1

$CO/N=C(\C(=O)NC1C(=O)N2C(C(=O)OCc3oc(=O)oc3C)=C(CSc3nc(C)ns3)CS[C@H]12)c1cscn1$

Reaction #62544

Ausbeute 62.3%DOI: 10.6084/m9.figshare.5104873.v1

$CO/N=C(\C(=O)NC1C(=O)N2C(C(=O)OCc3oc(=O)oc3C)=C(CSc3ncns3)CS[C@H]12)c1cscn1$

Reaction #62545

Ausbeute 31.0%DOI: 10.6084/m9.figshare.5104873.v1

C=CC(=O)NCOS(=O)(=O)CCC.C=CC(=O)[O-].[Na+].[Na]

Reaction #82136

sodium acrylate sodium acrylamidomethylpropanesulfonate

DOI: 10.6084/m9.figshare.5104873.v1

CC(O)C1C(=O)N2C(C(=O)[O-])=C(SC3COC(COC(N)=O)C3)C(C)C12.[Na+]

Reaction #83043

desired product

Ausbeute 67.0%DOI: 10.6084/m9.figshare.5104873.v1

CC(O)C1C(=O)N2C(C(=O)[O-])=C(SC3COC(COC(N)=O)C3)C(C)C12.[Na+]

Reaction #83044

desired product

Ausbeute 55.7%DOI: 10.6084/m9.figshare.5104873.v1

CC(O)C1C(=O)N2C(C(=O)[O-])=C(SC3COC(COc4ccccc4)C3)C(C)C12.[Na+]

Reaction #83047

desired product

Ausbeute 20.4%DOI: 10.6084/m9.figshare.5104873.v1

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