Reaktion #82136

ord-0f26b227783340298ec8bbe0e9982c6c

Reaktionsgleichung

C=CC(=O)NCOS(=O)(=O)CCC.[Na]
sodium acrylamidomethylpropanesulfonate
C=CC(=O)O
acrylic acid
[Na+].[OH-]
sodium hydroxide
O=S(=O)([O-])OOS(=O)(=O)[O-].[K+].[K+]
potassium persulfate
→
C=CC(=O)NCOS(=O)(=O)CCC.C=CC(=O)[O-].[Na+].[Na]
sodium acrylate sodium acrylamidomethylpropanesulfonate

Edukte

C=CC(=O)NCOS(=O)(=O)CCC.[Na]
sodium acrylamidomethylpropanesulfonate
C=CC(=O)O
acrylic acid
[Na+].[OH-]
sodium hydroxide
O=S(=O)([O-])OOS(=O)(=O)[O-].[K+].[K+]
potassium persulfate

Reagenzien

Keine

Lösungsmittel

O
water

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Temperaturunder cooling
  2. 2
    Sonstigeto prepare a homogeneous solution as an aqueous monomer/initiator solution

Vorschrift

36.1 g of acrylic acid was dissolved in 16.0 g of water and neutralized with 53.0 g of a 30 wt. % aqueous sodium hydroxide solution under cooling. Thereafter, 101.3 g of a 40% aqueous sodium acrylamidomethylpropanesulfonate solution was added thereto, and 10.7 g of a 2.8 wt. % aqueous potassium persulfate solution was added thereto to prepare a homogeneous solution as an aqueous monomer/initiator solution. Thereafter, the procedure of Example 4 was repeated to provide 93.5 g of a sodium acrylate/sodium acrylamidomethylpropanesulfonate copolymer. The resultant polymer was a granular material having a distorted shape of 550 μm in the average particle diameter as measured by sieving and a bulk density of 0.45 g/ml.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05621055uspto-grants-1997_04