Reaktion #12076

ord-ebe86df30b2441388fb356c07f9e4914

Reaktionsgleichung

C=CC(=O)[O-].[Na+]
sodium acrylate
CCO[Si](Cl)(OCC)OCC
chlorotriethoxysilane
→
C=CC(=O)[Si](OCC)(OCC)OCC
acryltriethoxysilane

Edukte

C=CC(=O)[O-].[Na+]
sodium acrylate
CCO[Si](Cl)(OCC)OCC
chlorotriethoxysilane

Reagenzien

Keine

Lösungsmittel

C1CCOC1
THF
C1CCOC1
THF

Reaktionsbedingungen

Temperatur
-70°CELSIUS
Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Temperaturto warm up to room temperature
  2. 2
    SonstigeNaCl is removed by filtration and solution
  3. 3
    Sonstigeevaporated to dryness

Vorschrift

6.123 g (0.0651 mol) sodium acrylate is dissolved to 25 mL THF and cooled to −70° C. 12.8 mL (0.0651 mol, 12.938 g) chlorotriethoxysilane in THF (15 mL) is added dropwise to reaction solution. The solution is stirred for over night allowing it to warm up to room temperature. NaCl is removed by filtration and solution evaporated to dryness to result clear liquid, acryltriethoxysilane.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07098346B2uspto-grants-2006_08