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C=C(COC1CC2C3CCC4=CC(=O)C=CC4(C)C3(F)C(O)CC2(C)C1(O)C(=O)CCl)c1ccccc1
Reaction #199533
DOI: 10.1039/C8SC04228D
CC12C=CC(=O)C=C1CCC1C3CC(OCCOS(C)(=O)=O)C(O)(C(=O)CCl)C3(C)CC(O)C12F
Reaction #277169
DOI: 10.1039/C8SC04228D
CC12C=CC(=O)C=C1CCC1C3CC(OCC(=O)c4ccccc4)C(O)(C(=O)CCl)C3(C)CC(O)C12F
Reaction #285320
DOI: 10.1039/C8SC04228D
CC1(COC2CC3C4CCC5=CC(=O)C=CC5(C)C4(F)C(O)CC3(C)C2(O)C(=O)CCl)CO1
Reaction #392378
DOI: 10.1039/C8SC04228D
CCOC(COC1CC2C3CCC4=CC(=O)C=CC4(C)C3(F)C(O)CC2(C)C1(O)C(=O)CCl)OCC
Reaction #890274
DOI: 10.1039/C8SC04228D
C=C(C)CO[C@@H]1C[C@H]2[C@@H]3CCC4=CC(=O)C=C[C@]4(C)[C@@]3(F)[C@@H](O)C[C@]2(C)[C@@]1(O)C(=O)CCl
Reaction #1005554
21-chloro-9-fluoro-11β,17 -dihydroxy-16α-[(2-methyl-2-propenyl)oxy]pregna-1,4-diene-3,20-dione
DOI: 10.6084/m9.figshare.5104873.v1
CC1(CO[C@@H]2C[C@H]3[C@@H]4CCC5=CC(=O)C=C[C@]5(C)[C@@]4(F)[C@@H](O)C[C@]3(C)[C@@]2(O)C(=O)CCl)CO1
Reaction #1005555
21-chloro-9-fluoro-11β,17-dihydroxy-16α-[(2-methyloxiranyl)methoxy]pregna-1,4-diene-3,20-dione
Ausbeute 14.8%DOI: 10.6084/m9.figshare.5104873.v1
CCOC(CO[C@@H]1C[C@H]2[C@@H]3CCC4=CC(=O)C=C[C@]4(C)[C@@]3(F)[C@@H](O)C[C@]2(C)[C@@]1(O)C(=O)CCl)OCC
Reaction #1005556
21-chloro-16α-(2,2-diethoxyethoxy)-9-fluoro-11β,17-dihydroxypregna-1,4-diene-3,20-dione
DOI: 10.6084/m9.figshare.5104873.v1
C=C(CO[C@@H]1C[C@H]2[C@@H]3CCC4=CC(=O)C=C[C@]4(C)[C@@]3(F)[C@@H](O)C[C@]2(C)[C@@]1(O)C(=O)CCl)c1ccccc1
Reaction #1005562
21-chloro-9-fluoro-11β,17-dihydroxy-16α-[(2-phenyl-2-propenyl)oxy]-pregna-1,4-diene-3,20-dione
Ausbeute 47.6%DOI: 10.6084/m9.figshare.5104873.v1
C[C@]12C=CC(=O)C=C1CC[C@H]1[C@@H]3C[C@@H](OCC4(c5ccccc5)CO4)[C@](O)(C(=O)CCl)[C@@]3(C)C[C@H](O)[C@@]12F
Reaction #1005563
21-chloro-9-fluoro-11β,17-dihydroxy-16α-[(2-phenyloxiranyl)methoxy]pregna-1,4-diene-3,20-dione
Ausbeute 116.5%DOI: 10.6084/m9.figshare.5104873.v1
C[C@]12C=CC(=O)C=C1CC[C@H]1[C@@H]3C[C@@H](OCC(=O)c4ccccc4)[C@](O)(C(=O)CCl)[C@@]3(C)C[C@H](O)[C@@]12F
Reaction #1005564
21-chloro-9-fluoro-11β,17-dihydroxy-16α-(2-oxo-2-phenylethoxy)pregna-1,4-diene-3,20-dione
Ausbeute 51.3%DOI: 10.6084/m9.figshare.5104873.v1
C[C@]12C=CC(=O)C=C1CC[C@H]1[C@@H]3C[C@@H](OCCOS(C)(=O)=O)[C@](O)(C(=O)CCl)[C@@]3(C)C[C@H](O)[C@@]12F
Reaction #1005565
21-Chloro-9-fluoro-11β,17-dihydroxy-16α-(2-mesyloxyethoxy)pregna-1,4-diene-3,20-dione
DOI: 10.6084/m9.figshare.5104873.v1
CC(O[C@@H]1C[C@H]2[C@@H]3CCC4=CC(=O)C=C[C@]4(C)[C@@]3(F)[C@@H](O)C[C@]2(C)[C@@]1(O)C(=O)CCl)C(=O)c1ccccc1
Reaction #1005569
21-Chloro-9-fluoro-11β,17-dihydroxy-16α-[(3-oxo-3-phenylprop-2-yl)oxy]pregna-1,4-diene-3,20-dione
DOI: 10.6084/m9.figshare.5104873.v1
CC12C=CC(=O)C=C1CCC1C3CC(OCC4(c5ccccc5)CO4)C(O)(C(=O)CCl)C3(C)CC(O)C12F
Reaction #1218809
DOI: 10.1039/C8SC04228D