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CC(=O)O[C@H]1CC[C@@]2(C)C(=CC[C@@H]3[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]32)C1
Reaction #2078
3β-acetoxy-5-androstene-17-one
DOI: 10.6084/m9.figshare.5104873.v1
C[C@]12CC[C@H](OC(=O)OCc3ccccc3)CC1=CC[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]12
Reaction #2079
3β-benzyloxycarbonyloxy-5-androsten-17-one
DOI: 10.6084/m9.figshare.5104873.v1
CC(=O)O.C[C@]12CC[C@H](OCO)CC1=CC[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]12
Reaction #2080
desired compound
DOI: 10.6084/m9.figshare.5104873.v1
CC(=O)OC1CC[C@@]2(C)C(=CC[C@@H]3[C@@H]2CC[C@]2(C)C(O)CC[C@@H]32)C1
Reaction #2766
crude title compound
DOI: 10.6084/m9.figshare.5104873.v1
C[C@]12CC[C@H]3[C@@H](C[C@@H]4O[C@@]45CCCC[C@]35C)[C@@H]1CCC2=O
Reaction #70379
5α,6α-epoxyandrostan-17-one
DOI: 10.6084/m9.figshare.5104873.v1
CC(=O)O[C@H]1CC[C@@]2(C)C(CC(=O)[C@@H]3[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]32)C1
Reaction #70385
3β-acetoxyandrostane-7,17-dione
Ausbeute 60.0%DOI: 10.6084/m9.figshare.5104873.v1
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Reaction #77235
compound 250
DOI: 10.6084/m9.figshare.5104873.v1
CC(C)(C)[Si](C)(C)O[C@H]1CC[C@@]2(C)C(=C[C@H](O)[C@H]3[C@@H]4[C@@H]5C[C@@H]5C(=O)[C@@]4(C)CC[C@@H]32)C1
Reaction #93687
3β-(tert.-butyldimethylsilyloxy)-7β-hydroxy-15β,16β-methylene-5-androsten-17-one
Ausbeute 78.9%DOI: 10.6084/m9.figshare.5104873.v1
C[C@]12CC[C@H](O[Si](Cc3ccccc3)(Cc3ccccc3)Cc3ccccc3)CC1=C[C@H](O)[C@H]1[C@@H]3[C@@H]4C[C@@H]4C(=O)[C@@]3(C)CC[C@@H]12
Reaction #93688
3β-tribenzylsilyloxy-7β-hydroxy-15β,16β-methylene-5-androsten-17-one
Ausbeute 89.8%DOI: 10.6084/m9.figshare.5104873.v1
C[C@]12CC[C@H]3[C@@H]([C@@H](O)[C@H]4O[C@]45C[C@@H](O[Si](Cc4ccccc4)(Cc4ccccc4)Cc4ccccc4)CC[C@]35C)[C@@H]1[C@@H]1C[C@@H]1C2=O
Reaction #93695
3β-tribenzylsilyloxy-5,6β-epoxy-7β-hydroxy-15β,16β-methylene-5β-androstan-17-one
DOI: 10.6084/m9.figshare.5104873.v1
CCOC(=O)C1CCC2(C)C(=CC(=O)C3C4CCC(=O)C4(C)CCC32)C1
Reaction #198415
DOI: 10.1039/C8SC04228D
CC12CCC(O)CC1=CCC1C2CCC2(C)C(=NC3CC3)CCC12
Reaction #247913
DOI: 10.1039/C8SC04228D
CC12CCC(O)CC1CCC1C2CCC2(C)C(=O)CCC12F
Reaction #271438
DOI: 10.1039/C8SC04228D
CC(=O)OC1CCC2(C)C(CC(=O)C3C4CCC(=O)C4(C)CCC32)C1
Reaction #277883
DOI: 10.1039/C8SC04228D
CC12CCC3C(CC=C4CC(O[Si](C)(C)C(C)(C)C)CCC43C)C1CCC2=O
Reaction #282677
DOI: 10.1039/C8SC04228D
[C-]#[N+]C(C)=C1CCC2C3CC=C4CC5(CCC4(C)C3(O)CCC12C)OCCO5
Reaction #300169
DOI: 10.1039/C8SC04228D
C[C@]12CCC(=O)C[C@@H]1CC[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@]12F
Reaction #346402
14α-Fluoro-5α-androstane-3,17-dione
DOI: 10.6084/m9.figshare.5104873.v1
C[C@]12CCC(=O)C=C1CC[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@]12F
Reaction #346404
solid
Ausbeute 99.6%DOI: 10.6084/m9.figshare.5104873.v1
CC(=O)OC1CC[C@@]2(C)C(=CC[C@@H]3[C@@H]2CC[C@]2(C)C(O)CC[C@@H]32)C1
Reaction #347223
crude title compound
DOI: 10.6084/m9.figshare.5104873.v1
CCOC(=O)C(C#N)=C1CCC2C3CC=C4CC5(CCC4(C)C3(O)CCC12C)OCCO5
Reaction #392949
DOI: 10.1039/C8SC04228D
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