反应 #9846

反应方程式

oxygene

4-chlorotoluene

hexahydro-1,3,5-trihydroxy-1,3,5-triazine-2,4,6-trione

→

4-chlorobenzoic acid

4-chlorotoluene

溶剂

acetic acid

反应条件

实验过程

A mixture of 0.380 g of 4-chlorotoluene, 0.027 g of hexahydro-1,3,5-trihydroxy-1,3,5-triazine-2,4,6-trione (5% by mole relative to 4-chlorotoluene), 5 g of acetic acid and 0.004 g of cobalt(II) acetate.4H2O was stirred at 100° C. in an atmosphere of oxygene gas (1 atm=0.1 MPa) for 14 hours. The resulting product in the reaction mixture was analyzed by gas chromatography and was found to yield 4-chlorobenzoic acid in 99% yield at 100% conversion of 4-chlorotoluene.

来源