反应 #94252

反应方程式

pyridine

1,3-dimethyl-3(ethoxycarbonylperoxy)butyl chloroformate

ethanol

→

1,3-Dimethyl-3-(ethoxycarbonylperoxy)butyl ethyl carbonate

溶剂

diethyl ether

diethyl ether

反应条件

实验过程

To a solution of 24.4 g. (0.0786 mole) of (86.4%) 1,3-dimethyl-3(ethoxycarbonylperoxy)butyl chloroformate in 100 ml of diethyl ether, cooled at 10°±1° C was added a solution of 4.6 g (0.1 mole) of ethanol and 7.9 g. (0.1 mole) of pyridine in 25 ml of diethyl ether over a period of 20 minutes.

来源