反应 #742264

ord-4848b3a291ef4645b861f485a2887eb0

反应方程式

O=C(OCCOCCOC(=O)C(=O)c1ccccc1)C(=O)c1ccccc1
Irgacure 754
CC(C)(O)C(=O)c1ccc(OCCO)cc1
Irgacure 2959
CSc1ccc(C(=O)C(C)(C)N2CCOCC2)cc1
Irgacure 907
CCC(Cc1ccccc1)(C(=O)c1ccc(N2CCOCC2)cc1)N(C)C
Irgacure 369
→
CC(C)(O)C(=O)c1ccccc1
2-hydroxy-2-methyl-1-phenyl-propane-1-on

反应物

O=C(OCCOCCOC(=O)C(=O)c1ccccc1)C(=O)c1ccccc1
Irgacure 754
CC(C)(O)C(=O)c1ccc(OCCO)cc1
Irgacure 2959
CSc1ccc(C(=O)C(C)(C)N2CCOCC2)cc1
Irgacure 907
CCC(Cc1ccccc1)(C(=O)c1ccc(N2CCOCC2)cc1)N(C)C
Irgacure 369

试剂

FC1=C=C(F)[C](n2cccc2)C=C1.FC1=C=C(F)[C](n2cccc2)C=C1.[CH]1C=CC=C1.[CH]1C=CC=C1.[Ti]
Irgacure 784

反应条件

详细条件
See reaction.notes.procedure_details.

实验过程

Other examples are Irgacure 2959, Irgacure 127, Irgacure 907, Irgacure 369, Irgacure 379, Darocur TPO, Irgacure 819, Irgacure 784, Irgacure OXE01, Irgacure OXE02, and Irgacure 754 (all are manufactured by Ciba Specialty Chemicals).

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US08070968B2uspto-grants-2011_12