反应 #65882

反应方程式

allylglycidyl ether

allyldimethoxysilane

→

4,4-dimethoxy-7-glycidoxy-4-sila-1-heptene

溶剂

isopropanol

反应条件

后处理

1. 1
   workup.ADDITIONwere added to the flask
2. 2
   其他the solution was further reacted for 2 hrs
3. 3
   其他the reaction
4. 4
   workup.DISTILLATIONVacuum distillation (83°-85° C.) of the product mixture

实验过程

Using the same apparatus and procedure described in EXAMPLE 1, 12.1 g (0.11 mmol) of allylglycidyl ether and 60 μl of 1% chloroplatinic acid in isopropanol were added to the flask. Through the dropping funnel was added dropwise 6.6 g (0.05 mmol) of allyldimethoxysilane at 80° C. and the solution was further reacted for 2 hrs to complete the reaction. Vacuum distillation (83°-85° C.) of the product mixture gave 5.3 g (43.5%) of 4,4-dimethoxy-7-glycidoxy-4-sila-1-heptene.

来源