反应 #64059

ord-add4263e916e4d10b749dbf163e97500

反应方程式

CCCCSCc1c(C)cc(C)c(C2CC(=O)C(C(=O)CCC)=C(O)C2)c1C
2-butyryl-5-[3-(n-butylthiomethyl)-2,4,6-trimethylphenyl]-3-hydroxycyclohex-2-en-1-one
CCON.Cl
ethoxyamine hydrochloride
→
CCCCSCc1c(C)cc(C)c(C2CC(=O)C(C(CCC)=NOCC)=C(O)C2)c1C
5-[3-(n-Butylthiomethyl)-2,4,6-trimethylphenyl]-2-[1-(ethoxyimino)butyl]-3-hydroxycyclohex-2-en-1-one

反应物

CCCCSCc1c(C)cc(C)c(C2CC(=O)C(C(=O)CCC)=C(O)C2)c1C
2-butyryl-5-[3-(n-butylthiomethyl)-2,4,6-trimethylphenyl]-3-hydroxycyclohex-2-en-1-one
CCON.Cl
ethoxyamine hydrochloride
—
( iv )

试剂

无

反应条件

详细条件
See reaction.notes.procedure_details.

实验过程

5-[3-(n-Butylthiomethyl)-2,4,6-trimethylphenyl]-2-[1-(ethoxyimino)butyl]-3-hydroxycyclohex-2-en-1-one (59) was prepared from 2-butyryl-5-[3-(n-butylthiomethyl)-2,4,6-trimethylphenyl]-3-hydroxycyclohex-2-en-1-one and ethoxyamine hydrochloride following essentially the same procedure as that described in Example 1, part (iv).

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US04767879uspto-grants-1988_08