反应 #64058

ord-c9dfe726b8ed497881d13040ab88080b

反应方程式

CCCC(=O)C1=C(O)CC(c2c(C)cc(C)c(CO)c2C)CC1=O
2-butyryl-3-hydroxy-5-(3-hydroxymethyl-2,4,6-trimethylphenyl)cyclohex-2-en-1-one
CCON.Cl
ethoxyamine hydrochloride
→
CCCC(=NOCC)C1=C(O)CC(c2c(C)cc(C)c(CO)c2C)CC1=O
2-[1-(Ethoxyimino)butyl]-3-hydroxy-5-(3-hydroxymethyl-2,4,6-trimethylphenyl)cyclohex-2-en-1-one

反应物

CCCC(=O)C1=C(O)CC(c2c(C)cc(C)c(CO)c2C)CC1=O
2-butyryl-3-hydroxy-5-(3-hydroxymethyl-2,4,6-trimethylphenyl)cyclohex-2-en-1-one
CCON.Cl
ethoxyamine hydrochloride
—
( iv )

试剂

无

反应条件

详细条件
See reaction.notes.procedure_details.

实验过程

2-[1-(Ethoxyimino)butyl]-3-hydroxy-5-(3-hydroxymethyl-2,4,6-trimethylphenyl)cyclohex-2-en-1-one (51) was prepared from 2-butyryl-3-hydroxy-5-(3-hydroxymethyl-2,4,6-trimethylphenyl)cyclohex-2-en-1-one and ethoxyamine hydrochloride following essentially the same procedure as that described in Example 1, part (iv).

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US04767879uspto-grants-1988_08