反应 #64045

ord-a4ba08a8042b4ca1951bdb95b8c8499a

反应方程式

CCC(=O)C1=C(O)CC(c2c(C)cc(C)cc2C)CC1=O
3-hydroxy-5-mesityl-2-propionylcyclohex-2-en-1-one
O=S(=O)(O)Cl
chlorosulfonic acid
CNC
dimethylamine
CCON.Cl
ethoxyamine hydrochloride
→
CCON=C(CC)C1=C(O)CC(c2c(C)cc(C)c(S(=O)(=O)N(C)C)c2C)CC1=O
2-[1-(Ethoxyimino)propyl]-3-hydroxy-5-(2,4,6-trimethyl-3-dimethylsulfamoylphenyl)cyclohex-2-en-1-one

反应物

CCC(=O)C1=C(O)CC(c2c(C)cc(C)cc2C)CC1=O
3-hydroxy-5-mesityl-2-propionylcyclohex-2-en-1-one
O=S(=O)(O)Cl
chlorosulfonic acid
CNC
dimethylamine
CCON.Cl
ethoxyamine hydrochloride

试剂

无

反应条件

详细条件
See reaction.notes.procedure_details.

实验过程

2-[1-(Ethoxyimino)propyl]-3-hydroxy-5-(2,4,6-trimethyl-3-dimethylsulfamoylphenyl)cyclohex-2-en-1-one (11) was prepared from 3-hydroxy-5-mesityl-2-propionylcyclohex-2-en-1-one, chlorosulfonic acid, dimethylamine, and ethoxyamine hydrochloride following essentially the same procedure as that described in Example 5.

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US04767879uspto-grants-1988_08