反应 #56951

反应方程式

p-toluidine

2-(hydroxymethylene)cyclohexanone

→

6-Methyl-2,3,4,9-tetrahydro-1H-carbazol-1-one

反应条件

后处理

1. 1
   其他to give a tan solid

实验过程

6-Methyl-2,3,4,9-tetrahydro-1H-carbazol-1-one was prepared from p-toluidine and 2-(hydroxymethylene)cyclohexanone in a similar manner as described in Example 1 to give a tan solid. 1H-NMR (CDCl3): δ 8.65 (s, 1H), 7.43 (s, 1H), 7.30 (d, 1H), 7.20 (d, 1H), 2.98 (t, 2H), 2.65 (t, 2H), 2.45 (s, 3H), 2.26 (quint, 2H); MS m/z 220 (M+1).

来源