反应 #55673

ord-5e686666afb648aaaad97f3640882fb7

反应方程式

CC(=O)[O-]
acetate
CCCCCCCC(C)(C)Cl
dimethyloctyl chloride
C=CC(=C)CCC=C(C)C.Cl
myrcene hydrochloride
[Na+].[OH-]
sodium hydroxide
CC(=O)[O-].[Na+]
sodium acetate
→
CC(C)=CCC/C(C)=C/CO.CC(C)=CCC/C(C)=C\CO
nerol geraniol

反应物

CC(=O)[O-]
acetate
CCCCCCCC(C)(C)Cl
dimethyloctyl chloride
C=CC(=C)CCC=C(C)C.Cl
myrcene hydrochloride
[Na+].[OH-]
sodium hydroxide
CC(=O)[O-].[Na+]
sodium acetate

试剂

无

反应条件

详细条件
See reaction.notes.procedure_details.

实验过程

The dimethyloctyl chloride is then obtained by reacting the myrcene hydrochloride (neryl/geranyl chloride) with sodium acetate and saponifying the acetate with sodium hydroxide to produce nerol/geraniol. This is then hydrogenated to produce dimethyloctanol, which is treated with HCl in the presence of zinc chloride to produce the dimethyloctyl chloride.

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US04221742uspto-grants-1980_09