反应 #531839

反应方程式

5-allyl-2,2′-bithiophene

trichlorosilane

→

5-(3-Trichlorosilylpropyl)-2,2′-bithiophene

溶剂

toluene

反应条件

后处理

1. 1
   其他The hydrosilylation reaction of Example 1

实验过程

The hydrosilylation reaction of Example 1 was repeated using 18.7 g of 5-allyl-2,2′-bithiophene in place of 2-allylthiophene, 10 g of anhydrous toluene, 20 g of trichlorosilane, and 150 mg of Platinum Catalyst. 5-(3-Trichlorosilylpropyl)-2,2′-bithiophene was obtained as a colorless liquid: 1H NMR (CDCl3) δ 7.20 (dd, 1H, J=5.1, 1.2 Hz); 7.14 (dd, 1H, J=3.6, 0.9 Hz); 7.02 (m, 2H); 6.74 (d, 1H, J=3.6 Hz); 2.93 (t, 2H, J=7.2 Hz); 1.99 (m, 2H); 1.49 (m, 2H).

来源