反应 #514154

ord-11312da6a2834eb4a44313c189813ae9

反应方程式

OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
D-mannitol
OC[C@@H](O)[C@H](O)[C@@H](O)CO
xylitol
→
O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
D-glucose

反应物

OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
D-mannitol
OC[C@@H](O)[C@H](O)[C@@H](O)CO
xylitol

试剂

无

反应条件

详细条件
See reaction.notes.procedure_details.

后处理

  1. 1
    温度is heated for 30 minutes to 80° C. with 67.5 g (227 mmole) of BEPDIB
  2. 2
    workup.DISTILLATIONAfter the readily volatile constituents have been distilled off in vacuo (10-3Torr), 11.6 g (96%) of bp. 108° C./10-3Torr and [α]D20 9.7 (c=6, CCl4) and 9.2 g (91%) of viscous residue
  3. 3
    其他are obtained

实验过程

A mixture of 7.46 g (41 mmole) of D-mannitol and 6.2 g (41 mmole) of xylitol is heated for 30 minutes to 80° C. with 67.5 g (227 mmole) of BEPDIB. After the readily volatile constituents have been distilled off in vacuo (10-3Torr), 11.6 g (96%) of bp. 108° C./10-3Torr and [α]D20 9.7 (c=6, CCl4) and 9.2 g (91%) of viscous residue are obtained.

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US04172195uspto-grants-1979_10