反应 #50708

反应方程式

8-phenyloctyl chloride

sodium iodide

→

8-phenyloctyl iodide

溶剂

acetone

反应条件

后处理

1. 1
   温度was heated
2. 2
   温度under reflux for 20 hours
3. 3
   其他Evaporated
4. 4
   workup.ADDITIONwater (20 ml) added
5. 5
   萃取extracted with diethyl ether (20 ml)
6. 6
   其他The extracts were dried
7. 7
   过滤filtered
8. 8
   其他evaporated to a pale yellow liquid (5.5 g)
9. 9
   workup.DISTILLATIONDistilled

实验过程

A mixture of 8-phenyloctyl chloride (4.4 g), sodium iodide (5.34 g) and acetone (20 ml) was heated under reflux for 20 hours. Evaporated, water (20 ml) added and extracted with diethyl ether (20 ml). The extracts were dried, filtered and evaporated to a pale yellow liquid (5.5 g). Distilled to give 8-phenyloctyl iodide, b.p. 200° C. (air bath temperature) at 0.1 mBar.

来源