反应 #502059

ord-11d94e99141441139220eea2e5013c4c

反应方程式

C/C(=C\CO)CCC[C@H](C)CCC[C@H](C)CCCC(C)C
phytol
[H][H]
hydrogen
→
CC(C)CCCC(C)CCCC(C)CCCC(C)CCO
phytanol

反应物

C/C(=C\CO)CCC[C@H](C)CCC[C@H](C)CCCC(C)C
phytol
[H][H]
hydrogen

试剂

[Ni]
Raney nickel

反应条件

详细条件
See reaction.notes.procedure_details.

实验过程

Hydrogenation of phytol can also be accomplished using Raney nickel and hydrogen to yield phytanol as referenced in Bendavid, A., Burns, C. J., Leslie, D. F., Hashimoto, K., Ridley, D. D., Sandanayake, S., and Wieczorek L., J. Org. Chem. (2001), 66, 3709-3716; Kim, T., Chan, K. C, and Crooks, R. M., J. Am. Chem. Soc. (1997) 119, 189; and Jellum, E., Eldjarn, L., and Try, K., Acta Chem. Scand. (1966), 20, 2335.

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US08088395B2uspto-grants-2012_01