反应 #47736

ord-b51d7cb6b41e41718e3f39d76b7da4bc

反应方程式

O=C1CCCC(=O)O1
Glutaric anhydride
C#Cc1cccc(N)c1
3-ethynylaniline
C#Cc1cccc(NC(=O)CCCC(=O)O)c1
product
收率 99.0%
C#Cc1cccc(NC(=O)CCCC(=O)O)c1
4-(3-Ethynyl-phenylcarbamoyl)-butyric acid
收率 99.0%

反应条件

详细条件
See reaction.notes.procedure_details.

后处理

  1. 1
    其他was evaporated under reduced pressure

实验过程

Glutaric anhydride (215 mg, 1.9 mmol) was dissolved in anhydrous dichloromethane (7 ml) and followed by the addition of 3-ethynylaniline (200 mg, 1.7 mmol). The mixture was allowed to stir at room temperature for 6 hours before the solvent was evaporated under reduced pressure to provide the product as a white solid (363 mg, 99%);

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US07745229B2uspto-grants-2010_06