反应 #426620

ord-dca2ccc2ad8a46c58d986d10cdd67c67

反应方程式

O=S(=O)([O-])OOS(=O)(=O)[O-].[NH4+].[NH4+]
ammonium persulfate
[Na]
sodium
C1CO1
ethylene oxide
C=C(C)C(=O)O
methacrylic acid
C=Cc1ccccc1
styrene
C=C(C)C(=O)O
methacrylic acid
O=S(=O)([O-])OOS(=O)(=O)[O-].[NH4+].[NH4+]
ammonium persulfate
C=C(CC=Cc1ccccc1)C(=O)O.[Na]
styrene-methacrylic acid sodium
C1CO1.C=C(C)C(=O)O
methacrylic acid ethylene oxide

溶剂

反应条件

温度
75°CELSIUS
详细条件
See reaction.notes.procedure_details.

后处理

  1. 1
    其他to thereby obtain a white emulsion
  2. 2
    其他to react for 5 hours

实验过程

A reaction container to which a stirring rod and a thermometer had been set was charged with 683 parts of water, 11 parts of sodium salt of sulfuric acid ester of ethylene oxide adduct of methacrylic acid (ELEMINOL RS-30, product of Sanyo Chemical Industries Ltd.), 138 parts of styrene, 138 parts of methacrylic acid and 1 part of ammonium persulfate. The resultant mixture was stirred at 400 rpm for 15 min to thereby obtain a white emulsion. The white emulsion was heated to a system temperature of 75° C. and was allowed to react for 5 hours. Then, 30 parts of a 1% by mass aqueous ammonium persulfate solution was added to the reaction mixture, followed by aging at 75° C. for 5 hours, to thereby obtain an aqueous dispersion [particle dispersion liquid] of a vinyl resin (a copolymer of styrene-methacrylic acid-sodium salt of sulfuric acid ester of methacrylic acid-ethylene oxide adduct). The volume average particle diameter of the obtained [particle dispersion liquid] was found to be 0.14 μm, when measured using LA-920 (product of Horiba, Ltd.). Part of the [particle dispersion liquid] was dried to isolate resin.

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US08895217B2uspto-grants-2014_11