反应 #355780

反应方程式

1-ethyl-1H-1,2,4-triazole-5-carbaldehyde oxime

ethanol

→

title compound

(1-Ethyl-1H-1,2,4-triazol-5-yl)methylammonium acetate

反应条件

后处理

1. 1
   过滤The reaction mixture was filtered
2. 2
   浓缩concentrated in vacuo

实验过程

A mixture of 1-ethyl-1H-1,2,4-triazole-5-carbaldehyde oxime (6.17 g, 44 mmol), 10% palladium hydroxide on carbon (2.9 g) acetic acid (125 mL) and ethanol (125 mL) were stirred under an atmosphere of hydrogen for 14 hours. The reaction mixture was filtered and concentrated in vacuo to give the title compound (7.7 g) 1H-NMR (d6-DMSO) δ 1.32 (3H, t, J=7 Hz), 1.89 (3H, s), 3.89 (2H, br), 4.17 (2H, q, J=7 Hz), 7.80 (1H, s).

来源