反应 #348464

反应方程式

3,5-dinitro-4-chloro-o-toluic acid

phosphorus pentachloride

→

3,5-Dinitro-4-chloro-o-toluoyl Chloride

溶剂

benzene

反应条件

后处理

1. 1
   workup.DISSOLUTIONAfter the solids dissolve
2. 2
   workup.DISTILLATIONthe benzene is distilled
3. 3
   其他the phosphorus oxychloride is removed under reduced pressure
4. 4
   温度on chilling

实验过程

Ten grams of 3,5-dinitro-4-chloro-o-toluic acid is warmed on a water bath with 9.2 grams of phosphorus pentachloride and 30 ml. of benzene. After the solids dissolve, the benzene is distilled and the phosphorus oxychloride is removed under reduced pressure. The desired product as a residual oil solidifies on chilling.

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