反应 #3069

ord-bd82a5043a4441d6bb653b1731c79827

反应方程式

Cc1ccc(CO)cc1I
alcohol
Cc1ccc(CO)cc1I
3-iodo-4-methylbenzyl alcohol
→
Cc1ccc(C=O)cc1I
3-iodo-4-methylbenzaldehyde

反应物

Cc1ccc(CO)cc1I
alcohol
Cc1ccc(CO)cc1I
3-iodo-4-methylbenzyl alcohol

试剂

[O]=[Mn]=[O]
MnO2

溶剂

ClCCl
CH2Cl2

反应条件

详细条件
See reaction.notes.procedure_details.

实验过程

A mixture of 1.0 mmol of this alcohol and 5.0 mmol of MnO2 in 5 mL of CH2Cl2 was stirred for 16 h at rt. Chromatography provided 3-iodo-4-methylbenzaldehyde.

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US05731432uspto-grants-1998_03