反应 #2460335

ord-2c52ce0473ba490ba0fc185ddb73e220

反应条件

详细条件
See reaction.notes.procedure_details.

后处理

  1. 1
    其他The formed crystals were isolated by filtration
  2. 2
    其他dried overnight at 40° C. in vacuo
  3. 3
    其他Isolated yield: 84.1 gram (90%)

实验过程

To a clear solution of 75 g olanzapine free base in 1500 ml acetone, was added slowly 18.0 g glycolic acid in 100 ml acetone at room temperature. The resulting mixture was stirred at room temperature overnight. The formed crystals were isolated by filtration and dried overnight at 40° C. in vacuo. Isolated yield: 84.1 gram (90%). 1H-NMR confirms the molar ratio olanzapine:acid=1:1.

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US07459449B2uspto-grants-2008_12