反应 #2329023

ord-5476ed8f4c484b69985a606c133da8b0

反应方程式

CC(C)(C)c1ccc(S(=O)c2ccc(C(C)(C)C)cc2)cc1
bis(4-tert-butylphenyl) sulfoxide
CC(C)(C)c1ccc(Br)cc1
4-tert-butylbromobenzene
CC(C)(C)c1ccc([S+](c2ccc(C(C)(C)C)cc2)c2ccc(C(C)(C)C)cc2)cc1.[Br-]
tris(4-tert-butylphenyl)sulfonium bromide

溶剂

反应条件

详细条件
See reaction.notes.procedure_details.

后处理

  1. 1
    其他The target compound was obtained
  2. 2
    其他the procedure of Synthesis Example 1-1 aside
  3. 3
    其他in Synthesis Example 1-1
  4. 4
    萃取for extraction

实验过程

The target compound was obtained by following the procedure of Synthesis Example 1-1 aside from using bis(4-tert-butylphenyl) sulfoxide instead of the diphenyl sulfoxide and 4-tert-butylbromobenzene instead of the chlorobenzene in Synthesis Example 1-1, and increasing the amount of water for extraction.

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US07670751B2uspto-grants-2010_03