反应 #2314307

反应方程式

3-(4-acetoxy-3-methoxyphenyl)propene

Trimethoxysilane

trimethoxysilane

→

2-acetoxy-5-(3-trimethoxysilylpropyl)anisole

反应条件

后处理

1. 1
   其他An ice bath was used
2. 2
   温度to maintain the reaction mixture at a temperature of between 100 and 108° C
3. 3
   workup.WAITthe reaction mixture was held at 90° C. for 1 hour
4. 4
   workup.DISTILLATIONThe product was distilled under vacuum at 143° C.

实验过程

In the same reactor vessel, the 3-(4-acetoxy-3-methoxyphenyl)propene was heated to 80° C. and then charged with chloroplatinic acid (0.79 grams). Trimethoxysilane (1990 grams, 16.3 moles) was added with stirring to the reaction mixture over a period of 40 minutes. An ice bath was used to maintain the reaction mixture at a temperature of between 100 and 108° C. After the addition of the trimethoxysilane, the reaction mixture was held at 90° C. for 1 hour and then the mixture was cooled to room temperature. The product was distilled under vacuum at 143° C. and 1 mm Hg.

来源