反应 #2171067

ord-9ace9f1d9b2c4facbb2d2c8107525b9f

反应条件

详细条件
See reaction.notes.procedure_details.

后处理

  1. 1
    洗涤washed with water and brine
  2. 2
    干燥dried over sodium sulfate
  3. 3
    浓缩concentrated in vacuo
  4. 4
    其他The residue was purified by chromatography (5:1

实验过程

3-(2-Phenyloxyphenyl)propionic Acid. A mixture of 3-(2-hydroxyphenyl)propionic acid (0.57 g, 3.4 mmol), phenylbromide (0.4 ml, 3.37 mmol), and K2CO3 (2.5 g) in acetone (10 ml) was stirred at room temperature for 2 days. The mixture was diluted with 1:1 hexane/EtOAc (100 ml), washed with water and brine, dried over sodium sulfate and concentrated in vacuo. The residue was purified by chromatography (5:1 then 4:1 hexane/EtOAc) to yield phenyl 3-(2-phenyloxyphenyl)propionate (0.45 g, 1.30 mmol, 77%).

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US06716818B2uspto-grants-2004_04