反应 #2048516

ord-1a06191fa37f42d6922cccb6a3900418

反应方程式

CCC[CH2][Sn]([I])([CH2]CCC)[CH2]CCC
Bu3SnI
[F-].[K+]
KF
→
CCC[CH2][Sn]([F])([CH2]CCC)[CH2]CCC
Bu3SnF

反应物

CCC[CH2][Sn]([I])([CH2]CCC)[CH2]CCC
Bu3SnI
[F-].[K+]
KF

试剂

无

反应条件

详细条件
See reaction.notes.procedure_details.

实验过程

Bu3SnI will react on the column with KF to give Bu3SnF, which rapidly reacts with the silica. The purified product in ether is recovered and then dried on a vane pump. Bu3SnI+KFaq→Bu3SnF↓+Klaq

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US08415016B2uspto-grants-2013_04