反应 #2021

ord-51173d9d709c45cdbf8cf8891134c0bf

反应方程式

OC[C@@H](O)[C@H](O)[C@@H](O)CO
xylitol
OCC(O)C(O)C(O)CO
pentitol
OC[C@@H](O)C(O)[C@H](O)CO
D-arabitol
O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
glucose
OC[C@@H](O)C(O)[C@H](O)CO
D-arabitol
O=C(CO)[C@@H](O)[C@H](O)CO
D-xylulose
O=C[C@H](O)[C@@H](O)[C@H](O)CO
D-xylose

反应条件

详细条件
See reaction.notes.procedure_details.

后处理

  1. 1
    其他which are particularly well adapted to the crystallization of xylitol

实验过程

It is known from European Patent No. 421,882, of which the Applicant is proprietor, to obtain xylitol syrups having a xylitol content of 80% to 90%, the remainder being essentially composed of D-arabitol, pentitol of the natural D series of sugars. These syrups, which are not very viscous and which are particularly well adapted to the crystallization of xylitol, are obtained by microbiological conversion of glucose to D-arabitol, microbiological oxidation of D-arabitol, to D-xylulose, enzymatic isomerization of D-xylulose to D-xylose and then catalytic hydrogenation of the mixture of D-xylulose and D-xylose to xylitol and D-arabitol. These xylitol syrups, which do not contain L-arabitol or galactitol but only D-arabitol as accompanying polyol, permit easy extraction of three crops of pure xylitol crystals.

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US05728225uspto-grants-1998_03