反应 #1985930

ord-5fc9ade5d4114e549785e45ecb023f5f

反应方程式

CN(C)[C@@H]1C(=O)C(C(N)=O)=C(O)[C@@]2(O)C(=O)C3=C(O)c4c(O)ccc(Cl)c4[C@@H](O)[C@H]3C[C@@H]12
DMcT
→
CN(C)[C@@H]1C(=O)C(C(N)=O)=C(O)[C@@]2(O)C(=O)C3=C(O)c4c(O)ccc(Cl)c4[C@@H](O)[C@H]3C[C@@H]12.CN1CCCC1=O
DMcT NMP

反应物

CN(C)[C@@H]1C(=O)C(C(N)=O)=C(O)[C@@]2(O)C(=O)C3=C(O)c4c(O)ccc(Cl)c4[C@@H](O)[C@H]3C[C@@H]12
DMcT
—
( 1.5 )

试剂

无

溶剂

CN1CCCC1=O
NMP

反应条件

详细条件
See reaction.notes.procedure_details.

实验过程

One point five (1.5) g (0.01 mole) of DMcT monomer powder were dissolved in 5 g of NMP to obtain a yellowish transparent viscous DMcT-NMP solution. To this solution, 2.5 g (0.015 mole) of polyaniline powder in a de-doped reduced state ("ANILEAD" available from Nitto Denko Corp., Japan) were added and the combined solution was then heated at 80° C. in a sealed container, whose inner atmosphere was substituted by an inert gas, to obtain a black purple liquid.

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US05571292uspto-grants-1996_11