反应 #1960482

ord-e50dcea785a74c798fdc9732f3598bbf

反应方程式

C1CCSC1
thiacyclopentane
c1ccsc1
thiophene
CCCCS
butylthiol
c1ccsc1
Thiophene
CCCCCCCCS
Octylthiol
S
hydrogen sulfide
C=C(C)CC(C)(C)C
diisobutylene

反应条件

详细条件
See reaction.notes.procedure_details.

实验过程

Thiophene hydrodesulfurization proceeds in the first reactor. Because a catalyst with low hydrogenation activity was used, no thiacyclopentane or butylthiol production was found in the thiophene hydrogenation product. Octylthiol was also produced by reaction between diisobutylene and hydrogen sulfide generated by the hydrodesulfurization. In the second reactor, the octylthiol produced by the first reactor was hydrodesulfurized, yielding a model gasoline base with a total sulfur content of no greater than 10 ppm by weight.

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US08303805B2uspto-grants-2012_11