反应 #1946548

反应方程式

salicylic acid

formaldehyde

hydrochloric acid

→

salicylic acid formaldehyde

溶剂

water

反应条件

后处理

1. 1
   其他In a reactor fitted with a condenser, addition funnel and a mechanical stirrer
2. 2
   workup.ADDITIONis added
3. 3
   workup.ADDITIONDuring the addition
4. 4
   温度cooled to room temperature
5. 5
   过滤The resulting polymer precipitate is filtered
6. 6
   workup.DISSOLUTIONdissolved in water (200 mL)
7. 7
   workup.ADDITIONcontaining 50% aqueous sodium hydroxide (26 mL) for performance testing

实验过程

In a reactor fitted with a condenser, addition funnel and a mechanical stirrer, deionized water (300 g) is heated to 95° C. At this temperature, a mixture of powdered salicylic acid (40 g) and boric anhydride (0.2 g) is added. Aqueous formaldehyde (40%, 35 mL), pre-acidified with hydrochloric acid (6.5 mL, 1.19 density), is then added over 15 minutes. During the addition, the reaction temperature is maintained at 90-100° C. The reaction mixture is stirred for 60 minutes at 95° C. and then cooled to room temperature. The resulting polymer precipitate is filtered and dissolved in water (200 mL) containing 50% aqueous sodium hydroxide (26 mL) for performance testing.

来源