反应 #1925212

反应方程式

ammonia

methyl acrylate

→

tris(2-methoxycarbonylethyl)amine

收率 76.0%

反应条件

后处理

1. 1
   温度The resulting mixture was heated gradually to 25° C. over 20 hours
2. 2
   浓缩After concentration under reduced pressure
3. 3
   workup.DISTILLATIONthe residue was-purified by distillation under reduced pressure

实验过程

While vigorously stirring at 0° C., 5.00 g of 28% aqueous ammonia was added to 21.2 g of methyl acrylate. The resulting mixture was heated gradually to 25° C. over 20 hours. After concentration under reduced pressure, the residue was-purified by distillation under reduced pressure, whereby tris(2-methoxycarbonylethyl)amine was obtained (boiling point: 143° C./70 Pa, yield: 76%),

来源