反应 #1778017

ord-f5eb6c67d5314477a85ede477741ebf0

反应方程式

OC[C@@H](O)[C@H](O)[C@@H](O)CO
xylitol
CC(C)[O-].CC(C)[O-].CC(C)[O-].[Ga+3]
gallium isopropoxide
[Ga]
gallium
OC[C@@H](O)[C@H](O)[C@@H](O)CO.[Ga]
Gallium Xylitol

反应条件

详细条件
See reaction.notes.procedure_details.

后处理

  1. 1
    workup.ADDITIONby adding 0.25 mole

实验过程

Other 1:1 gallium complexes with polyalcohols can be prepared in a similar fashion by substituting another polyalcohol ligand for the xylitol ligand in this procedure. Similarly, the 2:1 gallium complex with a polyalcohol can be prepared by adding 0.25 mole, instead of 0.5 mole, of polyalcohol ligand to the heated anhydrous gallium isopropoxide solution in this procedure.

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US08153687B2uspto-grants-2012_04