反应 #1702025

ord-e8aff0b932484fa896b0b92742fb332a

反应方程式

O=S([O-])[O-].[NH4+].[NH4+]
ammonium sulphite
O=O
oxygen
O=S(=O)([O-])[O-].O=S([O-])[O-].[NH4+].[NH4+].[NH4+].[NH4+]
ammonium sulphate ammonium sulphite

试剂

反应条件

详细条件
See reaction.notes.procedure_details.

实验过程

In an embodiment, the present invention provides for a process for reducing nitrogen oxides and halogenated organic compounds in an incineration plant having at least one combustion chamber. The process comprises separating out fly ash using a dust collector. Water is added to and hydrochloric acid separated out in a first acid-operated scrubber. Water and ammonia are added so as to separate out sulphur dioxide in a second neutral or slightly acid-operated scrubber so as to form ammonium sulphite, a portion of the ammonium sulphite being reacted with oxygen so as to form an aqueous ammonium sulphate/ammonium sulphite solution. The aqueous ammonium sulphate/ammonium sulphite solution is introduced into an oxygen-containing smoke gas downstream of a secondary gas introduction area so as to decompose the ammonium sulphate and ammonium sulphite so as to form ammonia and sulphur dioxide. Ammonia, oxygen and nitrogen oxides are reduced in the smoke gas by selective non-catalytic reduction so as to produce nitrogen and water, the chloride-containing fly ash in the smoke gas reacting with sulphur dioxide, water and oxygen so as to produce sulphates and hydrochloric acid.

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US08765089B2uspto-grants-2014_07