反应 #1702020

反应方程式

Ethylidenenorbornene

Butyl ether

diethylaluminumchloride

→

Dicyclopentadiene Ethylidenenorbornene

溶剂

dicyclopentadiene

反应条件

后处理

1. 1
   其他was then capped with a septum
2. 2
   其他purged with nitrogen
3. 3
   workup.DISSOLUTIONto dissolve the solids

实验过程

Irganox™ 1010 (0.24 g, Ciba Specialty Chemical Corp, Tarrytown, N.Y.) and Irgafos™ 168 (0.72 g, Ciba) were placed in an oven-dried 125 mL Erlenmeyer flask which was then capped with a septum and purged with nitrogen. Ethylidenenorbornene (35.6 mL, 0.26 mol) was added and the mixture was stirred for several minutes to dissolve the solids. Butyl ether (2.4 mL) and 9.1 mL of a 10 vol % solution of diethylaluminumchloride in dicyclopentadiene were then added. This solution is denoted Mixture 4B.

来源