反应 #1687675

反应方程式

methanol

p-tert-butoxystyrene

p-methylstyrene

2,2'-azobis(methyl 2-methylpropionate)

→

p-tert-butoxystyrene p-methylstyrene

溶剂

1,4-dioxane

反应条件

后处理

1. 1
   其他reaction in a nitrogen stream at 80° for 6 hours
2. 2
   温度The reaction solution was cooled
3. 3
   其他crystallization
4. 4
   其他Precipitated crystals
5. 5
   过滤were filtered out
6. 6
   洗涤washed with methanol
7. 7
   其他dried in vacuo

实验过程

To a solution of 100 g (0.567 mol) of p-tert-butoxystyrene and 3.54 g (0.03 mol) of p-methylstyrene in 300 ml of 1,4-dioxane was added a catalytic amount of 2,2'-azobis(methyl 2-methylpropionate) to carry out reaction in a nitrogen stream at 80° for 6 hours. The reaction solution was cooled and poured into 5,000 ml of a methanol solution to cause crystallization. Precipitated crystals were filtered out, washed with methanol and dried in vacuo to give 92.3 g of poly-(p-tert-butoxystyrene/p-methylstyrene)as white powder. The polymer was found to have p-tert-butoxystyrene unit and p-methylstyrene unit in a molar ratio of ca. 95:5 based on 1H NMR. The weight-average molecular weight (Mw) was determined to be about 20,000 by GPC with polystyrene calibration.

来源