反应 #1528392

反应方程式

1,3-bis(2,6-diisopropylphenyl)-iminoimidazoline

cyclopentadienyltitanium trichloride

triethylamine

→

1,3-bis(2,6-diisopropylphenyl)-iminoimidazoline cyclopentadienyl titanium dichloride

收率 46.0%

溶剂

toluene

—

ligroin

toluene

反应条件

后处理

1. 1
   温度The suspension was heated
2. 2
   温度to reflux
3. 3
   过滤filtered hot
4. 4
   其他afforded yellow crystals, which
5. 5
   过滤were filtered
6. 6
   洗涤washed with cold ligroin

实验过程

To a suspension of 1,3-bis(2,6-diisopropylphenyl)-iminoimidazoline (2.03 g, 5.0 mmol) and cyclopentadienyltitanium trichloride (1.10 g, 5.0 mmol) in toluene (30 mL) was added triethylamine (0.8 mL, 5,7 mmol) at ambient temperature. After stiriring for 1 hour, the thick yellow-orange suspension was diluted with toluene (50 mL) and ligroin (120 mL). The suspension was heated to reflux and filtered hot. Cooling to approx. 4° C. afforded yellow crystals, which were filtered and washed with cold ligroin to give 1.34 g (46% yield) of NMR pure 1,3-bis(2,6-diisopropylphenyl)-iminoimidazoline cyclopentadienyl titanium dichloride.

来源