反应 #1483158

反应方程式

triethylamine

1-chlorooctane

→

triethyloctylammonium chloride

收率 24.1%

溶剂

acetonitrile

反应条件

后处理

1. 1
   其他A nitrogen-purged 500 ml flask
2. 2
   洗涤the residue was washed with heptane and ethyl acetate

实验过程

A nitrogen-purged 500 ml flask was charged with 28.96 g (0.286 mol) of triethylamine, 55.23 g (0.371 mol) of 1-chlorooctane and 78.11 g of acetonitrile. The mixture was stirred at 80° C. under nitrogen for 96 hours. The volatile constituents of the reaction mixture were then drawn off under reduced pressure and the residue was washed with heptane and ethyl acetate to obtain 10.34 g (0.069 mol) of triethyloctylammonium chloride (white hygroscopic salt). The yield was 24%, based on triethylamine.

来源