反应 #1470463

ord-787957dcabd74079aa945a7e3ffb6fdc

反应条件

详细条件
See reaction.notes.procedure_details.

实验过程

164.6 g (0.37 mol) of (4-carboxybutyl)triphenylphosphonium bromide were suspended in 700 ml of tetrahydrofuran. 101 g (0.9 mol) of potassium t-butylate in 150 ml of tetrahydrofuran were added and then 68 g (0.36 mol) of 11-hydroxy-2-undecanone in 50 ml of tetrahydrofuran were added After usual working up there were obtained 98 g of crude 5Z-6-methylpentadec-5-enoic acid.

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US06255276B1uspto-grants-2001_07