反应 #1470425

反应方程式

1-oxyl-2,2,6,6-tetramethyl-4-glycidyloxypiperidine

diethanolamine

→

title compound

收率 29.9%

1-Oxyl-2,2,6,6-tetramethyl-4-{2-hydroxy-3-[di(2-hydroxyethyl)amino]propoxy}piperidine

收率 29.9%

溶剂

water

反应条件

后处理

1. 1
   萃取The solution is then extracted with methylene chloride
2. 2
   萃取The methylene chloride extract
3. 3
   干燥is dried over anhydrous magnesium sulfate
4. 4
   过滤filter
5. 5
   浓缩concentrated
6. 6
   其他The crude reaction product
7. 7
   其他is purified by column chromatography

实验过程

A solution of 2.28 g (0.01 mol) of 1-oxyl-2,2,6,6-tetramethyl-4-glycidyloxypiperidine and 1.05 g (0.01 mol) of diethanolamine in 25 mL of water is stirred at ambient temperature for 16 hours. The solution is then extracted with methylene chloride. The methylene chloride extract is dried over anhydrous magnesium sulfate, filter and concentrated. The crude reaction product is purified by column chromatography to afford 1.0 g of the title compound as a red oil.

来源