反应 #1365696

反应方程式

cesium carbonate

Ascorbic acid

isopropyl alcohol

carbon dioxide

→

cesium ascorbate

收率 192.0%

溶剂

water

反应条件

后处理

1. 1
   workup.WAITAfter standing for several hours
2. 2
   过滤the precipitate was filtered
3. 3
   洗涤washed with isopropyl alcohol
4. 4
   其他dried

实验过程

Ascorbic acid (5 g, 28.4 mmol) was dissolved in 20 ml of water, followed by slow addition of cesium carbonate (4.63 g, 14.2 mmol) in the temperature range of 0 to 5° C. 40 ml of isopropyl alcohol was slowly added to the reaction mixture when the generation of carbon dioxide completely stopped. After standing for several hours, the precipitate was filtered and washed with isopropyl alcohol, and dried to give 8.4 g of the cesium ascorbate as a white solid (yield 95%).

来源