反应 #1340563

ord-50762937bfe84de5b8de680d0acea52e

反应方程式

c1ccc2c(c1)c1ccccc1c1ccccc21
Triphenylene
[Al+3].[Cl-].[Cl-].[Cl-]
AlCl3
CC(=O)Cl
CH3COCl
→
CC(=O)c1cccc2c3ccccc3c3ccccc3c12
acetyltriphenylene
收率 97.0%

反应物

c1ccc2c(c1)c1ccccc1c1ccccc21
Triphenylene
[Al+3].[Cl-].[Cl-].[Cl-]
AlCl3
CC(=O)Cl
CH3COCl

试剂

无

溶剂

ClCCl
CH2Cl2

反应条件

详细条件
See reaction.notes.procedure_details.

实验过程

Triphenylene (1 equivalent) is reacted at 0° C. with 2.1 equivalents of AlCl3 and 21.0 equivalents of CH3COCl in CH2Cl2. After stirring at room temp. for 3 hours, the reaction product (acetyltriphenylene) was obtained in 97% yield, and is used in step b).

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US08455112B2uspto-grants-2013_06