反应 #1328429

ord-62936200adf84aa086de629268aff89e

反应方程式

O=O
oxygen
Cc1ccc(C)cc1
p-xylene
CC(=O)ON1C(=O)c2ccccc2C1=O
N-acetoxyphthalimide
CC(=O)O
acetic acid
O=C(O)c1ccc(C(=O)O)cc1
terephthalic acid
Cc1ccc(C(=O)O)cc1
p-toluic acid

反应条件

详细条件
See reaction.notes.procedure_details.

实验过程

A mixture of 2 mmol of p-xylene, 0.2 mmol of N-acetoxyphthalimide, 0.01 mmol of cobalt(II) acetate and 2 ml of acetic acid was stirred at 100° C. in an atmosphere of oxygen gas (1 atm=0.1 MPa) for 14 hours and thereby yielded terephthalic acid and p-toluic acid in yields of 89% and 1%, respectively.

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US07115541B2uspto-grants-2006_10