反应 #1265345

ord-6a8c24ac6a7e4d08b0674a65affce1f6

反应方程式

[Fe+2].[O-2]
iron oxide
CC(O)C(=O)[O-].[K+]
potassium lactate
[Al+3].[Cl-].[Cl-].[Cl-]
aluminum chloride
CC(O)C(=O)[O-].[K+]
potassium lactate
CCCCCCCCCCCCCC(=O)N[C@@H](CCC(=O)[O-])C(=O)[O-].[Na+].[Na+]
sodium N-myristoyl-L-glutamate
CCCCCCCCCCCCCC(=O)N[C@@H](CCC(=O)[O-])C(=O)[O-].[Na+].[Na+]
sodium N-myristoyl-L-glutamate
O=S(=O)([O-])[O-].[Zn+2]
zinc sulfate
→
CCCCCCCCCCCCCC(=O)N[C@@H](CCC(=O)[O-])C(=O)[O-].CCCCCCCCCCCCCC(=O)N[C@@H](CCC(=O)[O-])C(=O)[O-].CCCCCCCCCCCCCC(=O)N[C@@H](CCC(=O)[O-])C(=O)[O-].[Al+3].[Al+3]
aluminum N-myristoyl-L-glutamate
CC(O)C(=O)[O-].CC(O)C(=O)[O-].[Zn+2]
zinc lactate
[Fe+2].[O-2]
iron oxide

反应物

[Fe+2].[O-2]
iron oxide
CC(O)C(=O)[O-].[K+]
potassium lactate
[Al+3].[Cl-].[Cl-].[Cl-]
aluminum chloride
CC(O)C(=O)[O-].[K+]
potassium lactate
—
17
CCCCCCCCCCCCCC(=O)N[C@@H](CCC(=O)[O-])C(=O)[O-].[Na+].[Na+]
sodium N-myristoyl-L-glutamate
CCCCCCCCCCCCCC(=O)N[C@@H](CCC(=O)[O-])C(=O)[O-].[Na+].[Na+]
sodium N-myristoyl-L-glutamate
O=S(=O)([O-])[O-].[Zn+2]
zinc sulfate

试剂

无

溶剂

O
water
O
water
O
water

反应条件

温度
60°CELSIUS
详细条件
See reaction.notes.procedure_details.

后处理

  1. 1
    workup.ADDITIONmixed
  2. 2
    workup.ADDITIONuntil well dispersed
  3. 3
    workup.ADDITIONthen added to the above mixture
  4. 4
    workup.ADDITIONmixed for 10 minutes
  5. 5
    workup.ADDITIONwas added dropwise
  6. 6
    温度heated at 50° C.
  7. 7
    workup.ADDITIONthen added to the above mixture
  8. 8
    workup.ADDITIONmixed for 10 minutes
  9. 9
    workup.STIRRINGWhile this was being stirred
  10. 10
    workup.ADDITIONwas added dropwise
  11. 11
    过滤The product was filtered with suction
  12. 12
    洗涤by rinsing with purified water
  13. 13
    其他a temperature of 100° C.
  14. 14
    其他The cake was crushed
  15. 15
    温度after cooling

实验过程

One hundred grams of red iron oxide pigment was added to 500 ml of water and mixed using a home type mixer until well dispersed. Four grams of sodium N-myristoyl-L-glutamate having an HLB value of 4 was dissolved in 50 ml of water heated at 60° C. then added to the above mixture and mixed for 10 minutes. While this was being stirred, 2 chemical equivalents of aluminum chloride aqueous solution, based on the sodium N-myristoyl-L-glutamate, was added dropwise. Four grams of potassium lactate having an HLB value of 17 was dissolved in 50 ml of water heated at 50° C. then added to the above mixture and mixed for 10 minutes. While this was being stirred, 2 chemical equivalents of zinc sulfate aqueous solution, based on the potassium lactate, was added dropwise. The product was filtered with suction using a Buchner funnel, followed by rinsing with purified water. The filter cake was then baked in an oven for two hours after the filter cake reaches a temperature of 100° C. to further dehydrate the filter cake. The cake was crushed and pulverized to a powder after cooling. This resulted in a red iron oxide pigment chemically immobilized with aluminum N-myristoyl-L-glutamate and zinc lactate.

来源

DOI: 10.6084/m9.figshare.5104873.v1专利: US07276113B2uspto-grants-2007_10