反应 #1106607

反应方程式

Trifluoroacetic acid

trifluoroacethydrazide

→

1,2-bis(trifluoroacetyl)hydrazine

溶剂

benzene

反应条件

后处理

1. 1
   温度the mixture was heated
2. 2
   温度under reflux for 2 h
3. 3
   其他A Dean and Stark trap was fitted
4. 4
   温度reflux
5. 5
   温度Reflux
6. 6
   其他was continued in the absence of the Dean and Stark trap (3 h)
7. 7
   其他(20 h)
8. 8
   过滤The resulting white solid was collected by filtration
9. 9
   其他dried in vacuum

实验过程

Trifluoroacetic acid (7.6 mL, 0.1 mol) was added to a stirred solution of trifluoroacethydrazide (12.8 g, 0.1 mol) in benzene (100 mL) and the mixture was heated under reflux for 2 h. A Dean and Stark trap was fitted, and reflux was continued for 3 h. Reflux was continued in the absence of the Dean and Stark trap (3 h) and then with the trap refitted (20 h). The resulting white solid was collected by filtration, dried in vacuum and identified as 1,2-bis(trifluoroacetyl)hydrazine (16.5 g, 73%). M.p. 173-175° C.

来源