Реакция #992720

Уравнение реакции

2,7-bis(acetylamino)thianthrene

hydrochloric acid

→

2,7-diaminothianthrene

Выход 91.0%

Растворители

ethanol

Условия реакции

Обработка

1. 1
   Температураwas heated
2. 2
   Температураunder reflux for 6 hours
3. 3
   Фильтрацияa precipitate was collected by filtration
4. 4
   workup.ADDITIONThe precipitate was added to a mixture of 13.5 ml of concentrated hydrochloric acid and 355 ml of water
5. 5
   Другоеthe insoluble matters were separated by filtration
6. 6
   workup.ADDITIONThe filtered mother liquor was poured into an aqueous solution of sodium hydroxide
7. 7
   Фильтрацияthe precipitate or 2,7-diaminothianthrene was collected by filtration

Методика

A mixture of 5.75 g (0.0174 mole) of 2,7-bis(acetylamino)thianthrene, 12 ml of concentrated hydrochloric acid, and 140 ml of ethanol was heated under reflux for 6 hours. The reaction mixture was cooled to room temperature and a precipitate was collected by filtration. The precipitate was added to a mixture of 13.5 ml of concentrated hydrochloric acid and 355 ml of water and the insoluble matters were separated by filtration. The filtered mother liquor was poured into an aqueous solution of sodium hydroxide and the precipitate or 2,7-diaminothianthrene was collected by filtration. The yield was 3.7 g (0.0158 mole, 91% yield) and the purity was 88.2 area % (HPLC, 254 nm).

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