Реакция #985592

ord-740902d564ae4dc9875a50fb861a96b0

Уравнение реакции

O=[N+]([O-])c1ccc2cccc3c2c1CC3
3-nitroacenaphthene
CCOC(C)=O
ethyl acetate
→
Nc1ccc2c3c(cccc13)CC2
5-Acenaphthylamine

Реактанты

O=[N+]([O-])c1ccc2cccc3c2c1CC3
3-nitroacenaphthene
CCOC(C)=O
ethyl acetate

Реагенты

[Pd]
Pd/C

Условия реакции

Подробные условия
See reaction.notes.procedure_details.

Обработка

  1. 1
    Другоеthe resulting amines were separated by recrystallization from cyclohexane/ethyl acetate

Методика

A mixture of 5 and 3-nitroacenaphthene was reduced with Pd/C in ethyl acetate under hydrogen at 40 psi pressure and the resulting amines were separated by recrystallization from cyclohexane/ethyl acetate.

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US07351743B1uspto-grants-2008_04