Реакция #831110

ord-34fd181b5d53438eb04702d5283ed332

Уравнение реакции

C=Cc1ccc(OC(C)(C)C)cc1
p-tert-butoxystyrene
C=Cc1ccc(Cl)cc1
p-chlorostyrene
C=Cc1ccc(Cl)cc1.C=Cc1ccc(OC(C)(C)C)cc1
p-tert-butoxystyrene p-chlorostyrene

Реагенты

Нет

Условия реакции

Подробные условия
See reaction.notes.procedure_details.

Обработка

  1. 1
    Другоеthe polymerization
  2. 2
    Другоеas described in Synthesis Example 1, (1),

Методика

Using p-tert-butoxystyrene (83.7 g, 0.475 mole) and p-chlorostyrene (3.5 g, 0.025 mole), the polymerization and the treatment were carried out in the same manner as described in Synthesis Example 1, (1), to give 75.9 g of poly(p-tert-butoxystyrene/p-chlorostyrene) as white powder having Mw 22000 (GPC with polystyrene calibration). The polymer was found to have p-tert-butoxystyrene unit and p-chlorostyrene unit in a molar ratio) of ca. 95:5 based on 1HNMR.

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US05558971uspto-grants-1996_09