Реакция #831109

ord-98d2d04da09844f981294385e6be763c

Уравнение реакции

C=Cc1ccc(OC(C)(C)C)cc1
p-tert-butoxystyrene
C=Cc1ccc(OC)cc1
p-methoxystyrene
C=Cc1ccc(OC(C)(C)C)cc1.C=Cc1ccc(OC)cc1
p-tert-butoxystyrene p-methoxystyrene

Реагенты

Нет

Условия реакции

Подробные условия
See reaction.notes.procedure_details.

Обработка

  1. 1
    Другоеthe polymerization and treatment
  2. 2
    Другоеas described in Synthesis Example 1, (1),

Методика

Using p-tert-butoxystyrene (77.6 g, 0.44 mole) and p-methoxystyrene (8.1 g, 0.06 mole), the polymerization and treatment were carried out in the same manner as described in Synthesis Example 1, (1), to give 77.1 g poly(p-tert-butoxystyrene/p-methoxystyrene) as white powder having Mw 20000 (GPC with polystyrene calibration). The polymer was found to have p-tert-butoxystyrene unit and p-methoxystyrene unit in a molar ratio of ca. 88:12 based on 1HNMR.

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US05558971uspto-grants-1996_09